The Volta Prize was originally established by Napoleon III during the Second French Empire in 1852 to honor Alessandro Volta, an Italian physicist noted for developing the electric battery. This international prize awarded 50,000 French francs to extraordinary scientific discoveries related to electricity. The prize was instituted by the Ministry of Public Instruction with the personal funding of the French Emperor, the selection committee was usually constituted by members of the French Academy of Sciences.

Alessandro Giuseppe Antonio Anastasio Volta was an Italian physicist and chemist who was a pioneer of electricity and power and is credited as the inventor of the electric battery and the discoverer of methane. He invented the voltaic pile in 1799, and reported the results of his experiments in 1800 in a two-part letter to the president of the Royal Society. With this invention Volta proved that electricity could be generated chemically and debunked the prevalent theory that electricity was generated solely by living beings. Volta's invention sparked a great amount of scientific excitement and led others to conduct similar experiments, which eventually led to the development of the field of electrochemistry.